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Temperature dependence of the ratios of the rate constants of hydroxylation of the cycloalkanes C6H12/C6D12and C5H10/C6H12in sulfuric acid

✍ Scribed by L. K. Volkova; E. S. Rudakov

Publisher: Springer
Year: 2008
Tongue: English
Weight: 114 KB
Volume: 44
Category: Article
ISSN: 0040-5760
DOI: 10.1007/s11237-009-9051-3

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## Abstract Recently, we have discovered the unusual inverse temperature dependence of the kinetic isotope effect (KIE) for the OH + __c__‐C~6~H~12~/__c__‐C~6~D~12~ reaction in water. Temperature increase causes a KIE increase; this is valid for both the Fenton system (I) and the HOONOH~2~O system