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Kinetics and mechanism of the reactions of C6H12, C5H10and C6D12cycloalkanes with peroxynitrous acid in aqueous solution and the gas phase

✍ Scribed by V. L. Lobachev; Ya. V. Matvienko; E. S. Rudakov

Publisher: Springer
Year: 2008
Tongue: English
Weight: 120 KB
Volume: 44
Category: Article
ISSN: 0040-5760
DOI: 10.1007/s11237-008-9013-1

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## Abstract Recently, we have discovered the unusual inverse temperature dependence of the kinetic isotope effect (KIE) for the OH + __c__‐C~6~H~12~/__c__‐C~6~D~12~ reaction in water. Temperature increase causes a KIE increase; this is valid for both the Fenton system (I) and the HOONOH~2~O system