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Kinetics and mechanisms of the reactions of CH with CH4, C2H6 and n-C4H10

โœ Scribed by Michael R. Berman; M.C. Lin

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
608 KB
Volume
82
Category
Article
ISSN
0301-0104

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The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms