✦ LIBER ✦

Kinetics and anomalous temperature dependence of the kinetic isotope effect of reactions of cycloalkanes C5H10, C6H12and C6D12with OH radicals in aqueous solutions

✍ Scribed by V. L. Lobachev; E. S. Rudakov; Ya. V. Matvienko; L. K. Volkova

Publisher: Springer
Year: 2008
Tongue: English
Weight: 100 KB
Volume: 44
Category: Article
ISSN: 0040-5760
DOI: 10.1007/s11237-008-9002-4

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics and mechanism of the reactions

Kinetics and mechanism of the reactions of C6H12, C5H10and C6D12cycloalkanes with peroxynitrous acid in aqueous solution and the gas phase

✍ V. L. Lobachev; Ya. V. Matvienko; E. S. Rudakov 📂 Article 📅 2008 🏛 Springer 🌐 English ⚖ 120 KB

Cage effect and inverse temperature depe

Cage effect and inverse temperature dependence of the kinetic isotope effect in the c-C6H12/c-C6D12 reaction with OH radicals in fenton and HOONOH2O systems

✍ Elisey S. Rudakov; Vladimir L. Lobachev; Larisa K. Volkova 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB 👁 2 views

## Abstract Recently, we have discovered the unusual inverse temperature dependence of the kinetic isotope effect (KIE) for the OH + __c__‐C~6~H~12~/__c__‐C~6~D~12~ reaction in water. Temperature increase causes a KIE increase; this is valid for both the Fenton system (I) and the HOONOH~2~O system

Temperature dependence of the ratios of

Temperature dependence of the ratios of the rate constants of hydroxylation of the cycloalkanes C6H12/C6D12and C5H10/C6H12in sulfuric acid

✍ L. K. Volkova; E. S. Rudakov 📂 Article 📅 2008 🏛 Springer 🌐 English ⚖ 114 KB

Kinetics of phenyl radical reactions wit

Kinetics of phenyl radical reactions with ethane and neopentane: Reactivity of C6H5 toward the primary C-H bond of alkanes

✍ J. Park; S. Gheyas; M. C. Lin 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 169 KB 👁 2 views

Temperature-dependent kinetics studies o

Temperature-dependent kinetics studies of the reactions of C2H5O2 and n-C3H7O2 radicals with NO

✍ Jürg Eberhard; Carleton J. Howard 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 571 KB

The rate coefficients for the gas-phase reactions of C,H,O;, and n-C3H,0, radicals with NO have been measured over the temperature range of (201 -403) K using chemical ionization mass spectrometric detection of the peroxy radical. The alkyl peroxy radicals were generated by reacting alkyl radicals w

Kinetics of phenyl radical reactions wit

Kinetics of phenyl radical reactions with propane, n-butane, n-hexane, and n-octane: Reactivity of C6H5 toward the secondary CH bond of alkanes

✍ J. Park; Liming Wang; M. C. Lin 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB 👁 1 views

## Abstract The kinetics of C~6~H~5~ reactions with __n__‐C~__n__~H~2__n__+2~ (__n__ = 3, 4, 6, 8) have been studied by the pulsed laser photolysis/mass spectrometric method using C~6~H~5~COCH~3~ as the phenyl precursor at temperatures between 494 and 1051 K. The rate constants were determined by k