Energy dependence of the fragmentation of some isomeric [C6H12]+˙ ions
✍ Scribed by Jan A. Herman; Yip-Hoi Li; Alex. G. Harrison
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 820 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Appearance energy and kinetic energy release measurements together with isotopic labelling have shown that the metastable molecular ion of 1-phenylpmpenol isomerizes into those of cinnamic alcohol and 3-phenylpropanal prior to loss of ketene. =C! labelling and thennodynamic considerations prove that
The low-energy fragmentation characteristics of the [H, ,C,N,O,]+' isomers [H,CNOJ+' (a), [H,C=N(O)OHJ+' (b), [H,CONO]+' (c), [HC(O)NHOH]+' (d) and [HC(OH)=NOH]+' (e) were studied in detail by metastable ion mass spectrometry. In agreement with most earlier observations, appearance energy measuremen