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Energy dependence of the fragmentation of ester enolate ions

โœ Scribed by Alex B. Young; Alex G. Harrison


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
440 KB
Volume
22
Category
Article
ISSN
1076-5174

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Fragmentation reactions of the enolate i
โœ Allen Donnelly; Swapan Chowdhury; Alex. G. Harrison ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 497 KB

The reaction of [OH]-with Zpentanone produces two enolate ions, (CH,CH,CH,COCH,]-and [CH,COCHCH,CHJ -, by proton abstraction from C(l) and C(3), respectively. Using deuterium isotopic labelling the fragmentation reactions of each enolate have been delineated for collisional activation at both high (