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Temperature Dependence of the Ratios of C—H (C—D) Bond Breaking Rates in Reactions of Cycloalkanes C5H10, C6H12, C6D12with Adamantyl Carbocations in Sulfuric Acid

✍ Scribed by E. S. Rudakov; L. K. Volkova

Book ID
111613106
Publisher
Springer
Year
2003
Tongue
English
Weight
77 KB
Volume
39
Category
Article
ISSN
0040-5760

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## Abstract Recently, we have discovered the unusual inverse temperature dependence of the kinetic isotope effect (KIE) for the OH + __c__‐C~6~H~12~/__c__‐C~6~D~12~ reaction in water. Temperature increase causes a KIE increase; this is valid for both the Fenton system (I) and the HOONOH~2~O system