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Technetium thiolate complexes as oxygen atom transfer catalysts

✍ Scribed by De Vries, Nadine; Jones, Alun G.; Davison, Alan

Book ID
125961280
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
937 KB
Volume
28
Category
Article
ISSN
0020-1669

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Cycloruthenated complexes as homogeneous
Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions
✍ Ksenia Parkhomenko; Laurent Barloy; Jean-Baptiste Sortais; Jean-Pierre Djukic; M 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 318 KB

Various cycloruthenated complexes were used as homogeneous catalysts for the atom-transfer radical addition of polyhalogenated compounds to several olefinic substrates. Yields obtained through conventional or microwave heating could reach high values (up to 98% with CBrCl 3 and 88% with CCl 4 ).