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Copper−Homoscorpionate Complexes as Active Catalysts for Atom Transfer Radical Addition to Olefins

✍ Scribed by Muñoz-Molina, José María; Caballero, Ana; Díaz-Requejo, M. Mar; Trofimenko, Swiatoslaw; Belderraín, Tomás R.; Pérez, Pedro J.

Book ID
126874607
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
108 KB
Volume
46
Category
Article
ISSN
0020-1669

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Cycloruthenated complexes as homogeneous
Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions
✍ Ksenia Parkhomenko; Laurent Barloy; Jean-Baptiste Sortais; Jean-Pierre Djukic; M 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 318 KB

Various cycloruthenated complexes were used as homogeneous catalysts for the atom-transfer radical addition of polyhalogenated compounds to several olefinic substrates. Yields obtained through conventional or microwave heating could reach high values (up to 98% with CBrCl 3 and 88% with CCl 4 ).