Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions

✍ Scribed by Ksenia Parkhomenko; Laurent Barloy; Jean-Baptiste Sortais; Jean-Pierre Djukic; Michel Pfeffer

• Book ID: 104097219
• Publisher: Elsevier Science
• Year: 2010
• Tongue: French
• Weight: 318 KB
• Volume: 51
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/j.tetlet.2009.12.011

✦ Synopsis

Various cycloruthenated complexes were used as homogeneous catalysts for the atom-transfer radical addition of polyhalogenated compounds to several olefinic substrates. Yields obtained through conventional or microwave heating could reach high values (up to 98% with CBrCl 3 and 88% with CCl 4 ).