Ruthenium vs. Osmium Complexes as Catalysts for Atom Transfer Radical Addition Reactions
✍ Scribed by Mariano A. Fernández-Zúmel; Gregor Kiefer; Katrin Thommes; Rosario Scopelliti; Kay Severin
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 322 KB
- Volume
- 2010
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The bimetallic ruthenium complex [(1,3,5‐__i__‐Pr~3~C~6~H~3~)Ru(μ‐Cl)~3~RuCl(C~2~H~4~)(PCy~3~)] has been synthesized by reaction of [(1,3,5‐__i__‐Pr~3~C~6~H~3~)RuCl~2~)]~2~ with one equivalent of PCy~3~ in the presence of ethylene. It can be used as a catalyst precursor for the controll
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