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Tandem Michael Addition/Ylide Epoxidation for the Synthesis of Highly Functionalized Cyclohexadiene Epoxide Derivatives

✍ Scribed by Wang, Qing-Gang; Deng, Xian-Ming; Zhu, Ben-Hu; Ye, Long-Wu; Sun, Xiu-Li; Li, Chuan-Ying; Zhu, Chun-Yin; Shen, Qi; Tang, Yong


Book ID
120799891
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
111 KB
Volume
130
Category
Article
ISSN
0002-7863

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## Abstract Treatment of Ξ±,β‐unsaturated ketones with the sulfonium salt (I) and the weak base Cs~2~CO~3~ results in efficient and stereoselective formation of cyclohexadiene epoxides like (III).