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ChemInform Abstract: Tandem Michael Addition/Ylide Epoxidation for the Synthesis of Highly Functionalized Cyclohexadiene Epoxide Derivatives.

✍ Scribed by Qing-Gang Wang; Xian-Ming Deng; Ben-Hu Zhu; Long-Wu Ye; Xiu-Li Sun; Chuan-Ying Li; Chun-Yin Zhu; Qi Shen; Yong Tang


Publisher
John Wiley and Sons
Year
2008
Weight
55 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract Treatment of Ξ±,β‐unsaturated ketones with the sulfonium salt (I) and the weak base Cs~2~CO~3~ results in efficient and stereoselective formation of cyclohexadiene epoxides like (III).