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Highly Selective Ylide-Initiated Michael Addition/Cyclization Reaction for Synthesis of Cyclohexadiene Epoxide and Vinylcyclopropane Derivatives

✍ Scribed by Zhu, Ben-Hu; Zhou, Rui; Zheng, Jun-Cheng; Deng, Xian-Ming; Sun, Xiu-Li; Shen, Qi; Tang, Yong

Book ID
118276080
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
803 KB
Volume
75
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Highly Selective Yl
ChemInform Abstract: Highly Selective Ylide-Initiated Michael Addition/Cyclization Reaction for Synthesis of Cyclohexadiene Epoxide and Vinylcyclopropane Derivatives.
✍ Ben-Hu Zhu; Rui Zhou; Jun-Cheng Zheng; Xian-Ming Deng; Xiu-Li Sun; Qi Shen; Yong πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 51 KB πŸ‘ 2 views

## Abstract Treatment of Ξ±,β‐unsaturated ketones with the sulfonium salt (I) and the weak base Cs~2~CO~3~ results in efficient and stereoselective formation of cyclohexadiene epoxides like (III).