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Synthetic utility of chiral tetrahydrofurans: Preparation of (1R, 3R, 5S)-1, 3-dimethyl-2, 9-dioxabicyclo[3.3.1]nonane

✍ Scribed by Yvan Guindon; Yves St. Denis; Sylvain Daigneault; Howard E. Morton

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 246 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84226-4

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✦ Synopsis

The use of the lodoetherlflcatlon reaction for the selective preparatlon of optically active w-2,4-dlsubstltuted tetrahydrofurans and the use of the latter compounds as precursors of s-1,3-dlols 1s exempllfled In the synthesis of (lR,3R,5S)-~-1,3-Dlmethyl-2,9-Dloxabicyclo [3.3.l]nonane(]).

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