The title compound was synthesized using a novel approach to form a C3.2.11 oxabicyclic ring system. This was achieved through an intramolecular C-H insertion of a carbenoid intermediate. ## Endo -1,3-dimethyl-2,9-dioxabicycloC3.3.11 nonane 1. isolated from Norway spruce, was found to be a host s
Short step synthesis of 1,3-dimethyl-2,9-dioxabicyclo [3.3.1] nonane: An insect attractant.
โ Scribed by Boonsong Kongkathip; Ngampong Kongkathip
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 101 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The title compound has been synthesized stereoselectively based on a new methodology for the construction of erythro-1,3-diols. Endo-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane (11, first isolated by Heemann and Francke in 1976 from Norway spruce attacked by the ambrosia beetle (Tgypodendron Lineatum
The use of the lodoetherlflcatlon reaction for the selective preparatlon of optically active w-2,4-dlsubstltuted tetrahydrofurans and the use of the latter compounds as precursors of s-1,3-dlols 1s exempllfled In the synthesis of (lR,3R,5S)-~-1,3-Dlmethyl-2,9-Dloxabicyclo [3.3.l]nonane(]).