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Synthetic studies towards the group A streptogramin antibiotics. Synthesis of the C9–C23 fragment

✍ Scribed by Chris J Brennan; Jean-Marc Campagne

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 106 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00973-x

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✦ Synopsis

A synthesis of the C9-C23 subunit of the group A streptogramin antibiotics is described. The synthesis incorporates a palladium-catalysed sp-sp coupling and a catalytic asymmetric vinylogous Mukaiyama aldol reaction to induce the stereogenic centre at C14.

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