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Synthetic studies toward the kempane diterpenes. Construction of a key tricyclic intermediate

✍ Scribed by Bao, Guanglin; Zhao, Liang; Burnell, D. Jean


Book ID
120605995
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
256 KB
Volume
3
Category
Article
ISSN
1477-0520

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Synthetic Studies Toward the Kempane Diterpenes: Preparation of the Ring System. -Starting with the Diels-Alder reaction of the diene(I) with (II) the adduct (III) is obtained, in which three of the four rings of kempanes are already in place. Transformations via the enone (VII) and stereoselective

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