Synthetic studies on the ingenane diterpenes. Construction of an ABC tricycle exhibiting trans-intrabridgehead stereochemistry

✍ Scribed by James H. Rigby; Jingdan Hu; Mary Jane Heeg

• Book ID: 104258992
• Publisher: Elsevier Science
• Year: 1998
• Tongue: French
• Weight: 287 KB
• Volume: 39
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(98)00243-3

✦ Synopsis

Intramolecular,

cycloaddition followed by alkoxide accelerated 1,5-H sigmatropy affords a functionalized ingenane tricycle possessing the critical inpur-intrabridgehead stereochemical relationship.