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Synthetic studies on tautomycin. Stereoselective construction of the C1–C26 region

✍ Scribed by Sei-ichi Nakamura; Masakatsu Shibasaki

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
310 KB
Volume
35
Category
Article
ISSN
0040-4039

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✦ Synopsis

A convcrgen~ stesuxon trolled synthesis of lhe cl-c26 podon of laulomyein has been

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✍ Amos B. Smith III; Quyan Lin; Kiyoshi Nakayama; Armen M. Boldi; Christopher S. B 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 218 KB

A convergent synthesis of the C(1-17) AB-ring subunit of the spongistatins, exceedingly scarce and highly ant]mitotic polyether macrolides, has been achieved via a one-flask dithiane bisalkylation, stereocontrolled spiroketalization, and Julia sulfone coupling/methylenation. © ]997 Elsevier Science