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Synthesis, Structure, and Reactivity of Chiral Rhenium Amido Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(NRR')

✍ Scribed by Dewey, Michael A. ;Andrew Knight, D. ;Arif, Atta ;Gladysz, J. A.


Publisher
Wiley (John Wiley & Sons)
Year
1992
Tongue
English
Weight
934 KB
Volume
125
Category
Article
ISSN
0009-2940

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✍ Stephen B. Falloon; Slawomir Szafert; Atta M. Arif; J. A. Gladysz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 280 KB 👁 2 views

Reaction of [(h 5 -C 5 Me 5 )Re-(NO)(PPh 3 )(CCH)] (1) and [Os 3 -(CO) 10 (NCCH 3 ) 2 ] (CH 2 Cl 2 , room temperature) gives the ReC 2 Os 3 complex [(h 5 -C 5 Me 5 )Re(NO)(PPh 3 )(CC)Os 3 -(CO) 10 (H)] (2, 78 %). The crystal structure shows that the hydride and ReCC terminus bridge the same two osmi