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Reactions of Diazo Compounds and Chiral Rhenium Alkylidene Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(CHR)]+ PF−6 A Versatile and Highly Stereoselective Route to Alkene Complexes

✍ Scribed by Wang, Van ;Gladysz, John A.


Publisher
Wiley (John Wiley & Sons)
Year
1995
Tongue
English
Weight
895 KB
Volume
128
Category
Article
ISSN
0009-2940

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Thermodynamic Enantioface-Binding Select
✍ Tang-Sheng Peng; Atta M. Arif; John A. Gladysz 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 German ⚖ 1015 KB

Reactions of monosubstituted alkenes RCH=CH, and [Re(q5-C,H5)(CH2CI,)(NO)(PPh3)]+BF; give complexes ([Re(q5-C5Hs)(CH2=CHR)(NO)(PPh,)l+BF; (la-g) in 63-99 %I yields as mixtures of (RS,SR)-and (RR,SS)-diastereoisomers ( l a (R