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Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(ROH)]⊕BF4⊖

✍ Scribed by Agbossou, Sénamé K. ;Smith, Whitney W. ;Gladysz, John A.


Publisher
Wiley (John Wiley & Sons)
Year
1990
Tongue
English
Weight
721 KB
Volume
123
Category
Article
ISSN
0009-2940

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✍ Virginie Comte; Marek M. Kubicki; Claude Moïse 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 312 KB 👁 1 views

Chloro-bridged bimetallic complexes (η 5 -C 5 H 5 )[η 5 -towards Lewis bases was studied; by exposure to CO or phosphanes, a facile cleavage of the chloro bridge C 5 H 4 PPh 2 MЈ(CO) 4 ]W(µ-Cl)X [X = Cl (3), X = H (4); MЈ = Cr, W] were prepared by photochemical irradiation of (η 5 -accompanied by re