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π/σ Equilibria in Metal Complexes of Organic Carbonyl Compounds; Synthesis and Structure of Chiral Rhenium Complexes [(η5-C5H5)Re(NO)(PPh3)(O CHAr)]X

✍ Scribed by Mr. N. Quirós Méndez; Dr. Atta M. Arif; Prof. J. A. Gladysz

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 328 KB
Volume: 29
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199014731

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Reaction of [(h 5 -C 5 Me 5 )Re-(NO)(PPh 3 )(CCH)] (1) and [Os 3 -(CO) 10 (NCCH 3 ) 2 ] (CH 2 Cl 2 , room temperature) gives the ReC 2 Os 3 complex [(h 5 -C 5 Me 5 )Re(NO)(PPh 3 )(CC)Os 3 -(CO) 10 (H)] (2, 78 %). The crystal structure shows that the hydride and ReCC terminus bridge the same two osmi