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Synthesis, Structure and Magnetic Properties of the Cobalt(II) 1,1′-Biphenyl-2,2′-dicarboxylate Hydroxide Chain Compound [Co3{O2CC12H8CO2}2.5(OH)(H2O)2]n

✍ Scribed by Jean-Michel Rueff; Sébastien Pillet; Gautier Bonaventure; Mohamed Souhassou; Pierre Rabu


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
240 KB
Volume
2003
Category
Article
ISSN
1434-1948

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Synthesis, Crystal Structure and Magneti
✍ Jean-Michel Rueff; Sébastien Pillet; Nicolas Claiser; Gautier Bonaventure; Moham 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 467 KB 👁 2 views

New 1D complexes are obtained from the reaction of 1,1Јbiphenyl-2,2Ј-dicarboxylic acid (diphenic acid) with KOH and [ under hydrothermal conditions. Compounds 1 and 2 are isostructural and their structure consists of stacked helical chains of octahedral metal(II) ions. Magnetic measurements show th