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Synthesis, Crystal Structure and Magnetic Properties of the Helical-Chain Compounds [M2(O2CC12H8CO2)2(H2O)8] [M = Cobalt(II), Nickel(II)]

✍ Scribed by Jean-Michel Rueff; Sébastien Pillet; Nicolas Claiser; Gautier Bonaventure; Mohamed Souhassou; Pierre Rabu

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
467 KB
Volume
2002
Category
Article
ISSN
1434-1948

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✦ Synopsis

New 1D complexes are obtained from the reaction of 1,1Јbiphenyl-2,2Ј-dicarboxylic acid (diphenic acid) with KOH and [

under hydrothermal conditions. Compounds 1 and 2 are isostructural and their structure consists of stacked helical chains of octahedral metal(II) ions. Magnetic measurements show that the Co II

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✍ Ally Aukauloo; Xavier Ottenwaelder; Rafael Ruiz; Yves Journaux; Yu Pei; Eric Riv 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 488 KB 👁 2 views

New homo-and heterometallic hexanuclear complexes of formula {[Cu(tmen) tetrakis(aminomethylene)methanetetrakis(oxamic acid), tmen = N,N,NЈ,NЈ-tetramethylethylenediamine, pmdien = N,N,N',N',N''-pentamethyldiethylenetriamine, and cyclam = 1,4,8,11-tetraazacyclotetradecane] have been synthesized. The