𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis, structure, and interconversion of chiral rhenium oxygen- and sulfur-bound sulfoxide complexes of formula [(η5-C5H5)Re(NO)(PPh3)(OS(Me)R)]+ X−; diastereoselective oxidations of coordinated methyl alkyl sulfides †

✍ Scribed by Otto, Michael; Boone, Brian J.; Arif, Atta M.; Gladysz, J. A.

Book ID
121186594
Publisher
The Royal Society of Chemistry
Year
2001
Tongue
English
Weight
412 KB
Volume
8
Category
Article
ISSN
1472-7773

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Attaching Metal-Capped sp Carbon Chains
Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries More Distorted than Planar Tetracoordinate
✍ Stephen B. Falloon; Slawomir Szafert; Atta M. Arif; J. A. Gladysz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 280 KB 👁 2 views

Reaction of [(h 5 -C 5 Me 5 )Re-(NO)(PPh 3 )(CCH)] (1) and [Os 3 -(CO) 10 (NCCH 3 ) 2 ] (CH 2 Cl 2 , room temperature) gives the ReC 2 Os 3 complex [(h 5 -C 5 Me 5 )Re(NO)(PPh 3 )(CC)Os 3 -(CO) 10 (H)] (2, 78 %). The crystal structure shows that the hydride and ReCC terminus bridge the same two osmi