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Synthesis, Structure, and Reactivity of Polymetallic C 3 OMe Complexes of the Formula (η 5 -C 5 Me 5 )Re(NO)(PPh 3 )(C⋮CC(OMe))M m (CO) n (M/ m / n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in Which a C 3 Chain Links Two Metals and Spans a Third

✍ Scribed by Falloon, Stephen B.; Weng, Weiqing; Arif, Atta M.; Gladysz, J. A.


Book ID
119938792
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
243 KB
Volume
16
Category
Article
ISSN
0276-7333

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Attaching Metal-Capped sp Carbon Chains
✍ Stephen B. Falloon; Slawomir Szafert; Atta M. Arif; J. A. Gladysz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 280 KB 👁 2 views

Reaction of [(h 5 -C 5 Me 5 )Re-(NO)(PPh 3 )(CCH)] (1) and [Os 3 -(CO) 10 (NCCH 3 ) 2 ] (CH 2 Cl 2 , room temperature) gives the ReC 2 Os 3 complex [(h 5 -C 5 Me 5 )Re(NO)(PPh 3 )(CC)Os 3 -(CO) 10 (H)] (2, 78 %). The crystal structure shows that the hydride and ReCC terminus bridge the same two osmi