Synthesis, Spectroscopic and Structural Studies of Metal—Metal-Bonded Metalloporphyrins
✍ Scribed by Jean-Michel Barbe; Roger Guilard
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 50 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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effect). Thus, in place of the one ligand-field transition (Eg + Tzg) customary for octahedral symmetry, three transitions can occur ( E l , ' > A l , , E l g + B z ~, and B1, + Eg for an octahedron extended in the z-direction), and these can be recognized in the reflectance spectra of most of the c
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## Abstract The complexation of a first‐generation dendrimer possessing a metal‐free octasubstituted phthalocyanine as its core has been carried out with copper and cobalt chlorides. In the case of the cobalt complex, the synthesis of the dendrimer has been pursued up to the eighth generation. The
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