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σ-Bonded Metal Carbonyl Cations and Their Derivatives: Syntheses and Structural, Spectroscopic, and Bonding Principles

✍ Scribed by Helge Willner; Friedhelm Aubke


Publisher
John Wiley and Sons
Year
2003
Weight
53 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Predominantly σ-Bonded Metal Carbonyl Ca
✍ Helge Willner; Friedhelm Aubke 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 244 KB 👁 1 views

## Abstract Predominantly σ‐bonded metal carbonyl cations (σ‐carbonyls) are conveniently generated in the Lewis superacid SbF~5~ or the conjugate Brønsted–Lewis superacid HFSbF~5~, primarily by solvolytic or reductive carbonylations. Thermally stable salts are formed with the fluoroantimonate(V) i