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Predominantly σ-Bonded Metal Carbonyl Cations (σ-Carbonyls): New Synthetic, Structural, and Bonding Concepts in Metal Carbonyl Chemistry

✍ Scribed by Helge Willner; Friedhelm Aubke

Publisher
John Wiley and Sons
Year
2003
Weight
54 KB
Volume
34
Category
Article
ISSN
0931-7597

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Predominantly σ-Bonded Metal Carbonyl Ca
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## Abstract Predominantly σ‐bonded metal carbonyl cations (σ‐carbonyls) are conveniently generated in the Lewis superacid SbF~5~ or the conjugate Brønsted–Lewis superacid HFSbF~5~, primarily by solvolytic or reductive carbonylations. Thermally stable salts are formed with the fluoroantimonate(V) i

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## Abstract The nature of the bonding in the above carbonyls was studied using the analysis of domain averaged Fermi holes (DAFH). The results straightforwardly confirm the conclusions of earlier theoretical studies in which the existence of direct metal–metal bond, anticipated for the above carbon