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Synthesis, Reactions, and Structural and NMR Features of [2.2]Metacyclophane Monoenes and Their Tricarbonylchromium and Cyclopentadienyliron(+) Complexes

โœ Scribed by Mitchell, Reginald H.; Zhang, Limin


Book ID
126167289
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
334 KB
Volume
64
Category
Article
ISSN
0022-3263

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## Abstract The synthesis of [4,5,6,8โ€^2^H~4~][2.2]metacyclophane (8) was achieved starting with 2,4,5,6โ€tetrafluoroisophthalic acid in eight steps in 2% total yield. ^1^H{^2^H} and ^13^C{^1^H} NMR spectra of 8 showed that the deuterium atoms were introduced at the desired positions.