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Synthesis, structure, and NMR spectra of a new ferrocenylbenzene tricarbonylchromium complex

✍ Scribed by Zhu, Ning; Zhang, Guang-Bin; Xie, Rui-Jun; Han, Li-Min; Hong, Hai-Long; Liu, Zhi-Sen; Suo, Quan-Ling

Book ID
126530005
Publisher
Taylor and Francis Group
Year
2011
Tongue
English
Weight
259 KB
Volume
64
Category
Article
ISSN
0095-8972

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Polycyclic compounds / Centropolyindans / Chromium arene complexes / Stereochemistry The reaction of 9H,10H-4b,9a([1,2]benzenomethano)indeno[l,2alindene (triptindan, TRIP) with Cr(CO)6 in Bu,O/THF (9:l) affords a monocomplex (A) together with two bis-Cr(C0)3 complexes (B and C ) and one tris-Cr(C0)3