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Synthesis, structure, and rearrangements of new tricarbonylchromium complexes of substituted heptalenes

✍ Scribed by Yu. A. Ustynyuk; O. I. Trifonova; A. V. Yatsenko; A. A. Borisenko; H. -J. Hansen; P. Uebelhart

Book ID
112387671
Publisher
Springer
Year
1994
Tongue
English
Weight
640 KB
Volume
43
Category
Article
ISSN
1573-9171

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## Abstract __ortho__‐Substituted [Cr(CO)~3~(benzaldehyde)] complexes are obtained __via__ nucleophilic addition of alkyl‐ and aryllithium reagents to a [Cr(CO)~3~(phenylmethaneimine)] complex followed by __endo__‐hydride abstraction with triphenylmethyl cation. This sequence, when carried out with