## Abstract __ortho__βSubstituted [Cr(CO)~3~(benzaldehyde)] complexes are obtained __via__ nucleophilic addition of alkylβ and aryllithium reagents to a [Cr(CO)~3~(phenylmethaneimine)] complex followed by __endo__βhydride abstraction with triphenylmethyl cation. This sequence, when carried out with
β¦ LIBER β¦
Resolution and asymmetric synthesis of ortho-substituted (benzaldehyde)tricarbonylchromium complexes
β Scribed by Alexakis, Alex; Mangeney, Pierre; Marek, Ilane; Rose-Munch, Francoise; Rose, Eric; Semra, Assia; Robert, Francis
- Book ID
- 126928501
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 402 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0002-7863
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## Synthesis of 2-Substituted 2-Arylmalonates via Tricarbonylchromium Complexes. -Biologically interesting title compounds of type (IV) are prepared in moderate to good yields. An attempt to induce stereoselectivity is best achieved with diester (Va). -(DEUTSCH,