ChemInform Abstract: Synthesis of 2-Substituted 2-Arylmalonates via Tricarbonylchromium Complexes.
β Scribed by J. DEUTSCH; M. BARTOSZEK; M. SCHNEIDER; V. ZABEL; H.-J. NICLAS
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Synthesis of 2-Substituted 2-Arylmalonates via Tricarbonylchromium
Complexes.
-Biologically interesting title compounds of type (IV) are prepared in moderate to good yields. An attempt to induce stereoselectivity is best achieved with diester (Va). -(DEUTSCH,
π SIMILAR VOLUMES
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## Synthesis of Substituted Bicyclo[2.2.2] octatrienes. -An efficient route to the title compounds involves Diels-Alder reactions of cyclohexadienediols with an activated acetylene, intermediate thiocarbonate formation [cf. conditions A)] and olefination according to B). -(WAGAMAN, M. W.;