ChemInform Abstract: Synthesis of Substituted Bicyclo[2.2.2]octatrienes.

✍ Scribed by M. W. WAGAMAN; E. BELLMANN; M. CUCULLU; R. H. GRUBBS

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 34 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199821083

✦ Synopsis

Synthesis of Substituted

Bicyclo[2.2.2]

octatrienes.

-An efficient route to the title compounds involves Diels-Alder reactions of cyclohexadienediols with an activated acetylene, intermediate thiocarbonate formation [cf. conditions A)] and olefination according to B). -(WAGAMAN, M. W.;