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ChemInform Abstract: Bicyclo[2.2.2]octylidene.

✍ Scribed by Qing Ye; Maitland Jones Jr.; Ting Chen; Philip B. Shevlin

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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## Synthesis of Substituted Bicyclo[2.2.2] octatrienes. -An efficient route to the title compounds involves Diels-Alder reactions of cyclohexadienediols with an activated acetylene, intermediate thiocarbonate formation [cf. conditions A)] and olefination according to B). -(WAGAMAN, M. W.;

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Cobalt-Catalyzed [4 + 2 + 2] Cycloadditions of Bicyclo[2.2.2]octadienes. -Norbornadiene (I) and the benzobarrelenes (IV) undergo cobalt-catalyzed [4 + 2 + 2] cycloaddition with the dienes (II) or (VI) to give the corresponding adducts. In contrast, analogous reaction of the bicyclo[3.2.1]octadeine

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v