ChemInform Abstract: Synthesis, Reactions, and Structural and NMR Features of [2.2]Metacyclophane Monoenes and Their Tricarbonylchromium and Cyclopentadienyliron(+) Complexes.
β Scribed by Reginald H. Mitchell; Limin Zhang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of 2,4-Diketoacids and Their Aqueous Solution Structures. -The synthesis of 2,4-diketoacids (IV) and (VII) is achieved by base-mediated condensation of oxalate (I) with methyl ketones (II) and (V) followed by ester hydrolysis. The diketoacids are shown to exist as 2-enols in CHCl 3 soluti