## Abstract For Abstract see ChemInform Abstract in Full Text.
Synthesis and Diels−Alder Reactions of 1,2-Dimethylene[2. n ]metacyclophanes
✍ Scribed by Yamato, Takehiko; Miyamoto, Shinpei; Hironaka, Tohru; Miura, Yoshinori
- Book ID
- 126158843
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 108 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1523-7060
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
This paper reports the syntheses of the previously unknown 4-S-dimethylene-12dioxane (1) and the symmetric bisperoxide 3,4,8,9-tetraoxa-l(6)-bicyclo[4.4.0]decene (2). 2 Compound 1 contains exocyclic diene and 12-dioxane moieties both of which can be madly functionalixed. The diene moiety can react w
## Abstract The title compounds 8 and 1 have been synthesized in three steps each from 1,2‐dibromo[2.2]paracyclophan‐1‐ene (2) and 1,2,9,10‐tetrabromo[2.2]paracyclophane‐1,9‐diene (4), respectively. Copper‐mediated coupling of vinyl bromides 2 and 4 with methyl‐ and phenylmagnesium bromide gives su
The synthesis and chemical reactivity in Diels-Alder reactions of the title compound 6 is described. When 6 was reacted with N-phenylmaleimide, a 3:1 mixture of isomers exo 14a and endo 14b was found, while with triazolinedione 13, a novel ferrocenyl heterocycle 15 was formed. The structures for 14b