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Synthesis and Diels-Alder reactions of 3-methylene-2-ferrocenylmethylenequinuclidine

✍ Scribed by Marcos Martínez García; Georgina Espinosa Pérez; Francisco Lara Ochoa; Raymundo Cruz-Almanza

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
384 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

The synthesis and chemical reactivity in Diels-Alder reactions of the title compound 6 is described. When 6 was reacted with N-phenylmaleimide, a 3:1 mixture of isomers exo 14a and endo 14b was found, while with triazolinedione 13, a novel ferrocenyl heterocycle 15 was formed. The structures for 14b and 15 were confirmed by X-ray diffraction analysis.

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