𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of β-l-fucopyranosyl phosphate andl-fucofuranosyl phosphates by the MacDonald procedure

✍ Scribed by Harry S. Prihar; Tsai Ji-Hsiung; Steven R. Wanamaker; Stephanie J. Duber; Edward J. Bethrman

Book ID
108308327
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
693 KB
Volume
56
Category
Article
ISSN
0008-6215

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Large-scale synthesis of β-l-fucopyranos
Large-scale synthesis of β-l-fucopyranosyl phosphate and the preparation of GDP-β-l-fucose
✍ Kim Adelhorst; George M. Whitesides 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 620 KB

A practical 15-mmol large-scale synthesis of beta-L-fucopyranosyl dicyclohexylammonium phosphate from L-fucose in 63% overall yield was developed. The synthesis took advantage of a neighboring Bz-2 group participating in a Koenigs-Knorr-like glycosylation. The sugar phosphate was transformed into th

Glycosyl imidates, 47. Stereospecific sy
Glycosyl imidates, 47. Stereospecific synthesis of α- and β-L-fucopyranosyl phosphates and of gdp-fucose via trichloroacetimidate
✍ Schmidt, Richard R. ;Wegmann, Barbara ;Jung, Karl-Heinz 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 459 KB

## Abstract Reaction of the benzyl‐ and acetyl‐protected α‐trichloroacetimidates 1 and 6α with dialkyl and diaryl phosphates in the presence of traces of acid affords stereoelectively the thermodynamically more stable α‐L‐fucopyranosyl phosphates 2, 7 and 8, respectively, in high yields. The use of