A practical 15-mmol large-scale synthesis of beta-L-fucopyranosyl dicyclohexylammonium phosphate from L-fucose in 63% overall yield was developed. The synthesis took advantage of a neighboring Bz-2 group participating in a Koenigs-Knorr-like glycosylation. The sugar phosphate was transformed into th
✦ LIBER ✦
Synthesis of β-L-fucopyranosyl phosphate from L-fucose orthoacetates
✍ Scribed by Ji-Hsiung Tsai; Edward J. Behrman
- Book ID
- 108308391
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 353 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0008-6215
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Large-scale synthesis of β-l-fucopyranos
✍
Kim Adelhorst; George M. Whitesides
📂
Article
📅
1993
🏛
Elsevier Science
🌐
English
⚖ 620 KB
Chemical synthesis of β-L-fucopyranosyl
✍
Prihar, H. S.; Behrman, E. J.
📂
Article
📅
1973
🏛
American Chemical Society
🌐
English
⚖ 774 KB
Glycosyl imidates, 47. Stereospecific sy
✍
Schmidt, Richard R. ;Wegmann, Barbara ;Jung, Karl-Heinz
📂
Article
📅
1991
🏛
John Wiley and Sons
🌐
English
⚖ 459 KB
## Abstract Reaction of the benzyl‐ and acetyl‐protected α‐trichloroacetimidates 1 and 6α with dialkyl and diaryl phosphates in the presence of traces of acid affords stereoelectively the thermodynamically more stable α‐L‐fucopyranosyl phosphates 2, 7 and 8, respectively, in high yields. The use of
Synthesis of β-l-fucopyranosyl phosphate
✍
Harry S. Prihar; Tsai Ji-Hsiung; Steven R. Wanamaker; Stephanie J. Duber; Edward
📂
Article
📅
1977
🏛
Elsevier Science
🌐
English
⚖ 693 KB
Synthesis of α-l-fucose-1-phosphate and
✍
Schanbacher, Floyd; Wilken, David R.
📂
Article
📅
1967
🏛
Elsevier Science
🌐
English
⚖ 282 KB
ChemInform Abstract: A Concise and Stere
✍
Andrew J. Norris; Tatsushi Toyokuni
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 31 KB
👁 2 views