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Synthesis of tritium labelled monomers and polymers

✍ Scribed by D.R. Burfield; C.M. Savariar

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 407 KB
Volume: 20
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(84)90058-2

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✦ Synopsis

The use of P205 for promoting the tritiation of various monomers and polymers has been investigated. Methyl methacrylate and vinyl acetate may be labelled at ambient temperatures by this procedure which is also applicable to labelling polystyrene and poly(~t-methylstyrene). Exchange labelling of polymer substrates is most conveniently carried out in chlorinated hydrocarbons. The rate of tritium exchange increases with solvent polarity and temperature. Monomers of high radiochemical purity may be derived from the thermal depolymerization of tritiated polystyrene, poly(~t-methylstyrene) and poly(methyl methacrylate).

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