𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of the new types of N-substituted aminomethylenebisorganophosphorus acids and their derivatives

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
165 KB
Volume
20
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The interaction of esters of trivalent organophosphorus acids containing PH and POSiMe~3~ fragments with various derivatives of formamide is proposed as convenient methods for the synthesis of new N‐substituted aminomethylenebisorganophosphorus acids and their derivatives with three‐, four‐, and five‐coordinated phosphorus. Also the new functionalized derivatives of the new aminomethylenebisphosphinic acids with substituted hydroxymethyl moieties are synthesized, and some properties of the obtained compounds are presented. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:319–324, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20552


📜 SIMILAR VOLUMES


Synthesis of new organophosphorus-substi
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB

## Abstract Nucleophilic addition of trimethylsilyl esters of hypophosphorus acid to trimethylsilyl ester and diethylamide of vinylsulfonic acid is proposed as convenient methods for the synthesis of new 2‐sulfonylethylphosphonites and their derivatives under mild conditions. Also the new functiona

Synthesis of new organophosphorus-substi
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB

## Abstract Nucleophilic or radical addition of trimethylsilyl esters of trivalent organophosphorus acids to various functionalized acrylates and their cyclic analogues is proposed as convenient methods for the synthesis of new 2‐trimethylsiloxycarbonyl‐substituted alkylphosphonites and their deriv

Synthesis of new types of N,N-disubstitu
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 154 KB

## Abstract Aminomethylation of several hydrospirophosphoranes and their derivatives, using chloro‐, alkoxy‐, and amino‐substituted methylamines of various structures, is proposed as the convenient method for the synthesis of new N,N‐disubstituted aminomethylspirophosphoranes. The unique reaction o