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Synthesis of new organophosphorus-substituted derivatives of functionalized propionates and their analogues

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
461 KB
Volume
19
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

Nucleophilic or radical addition of trimethylsilyl esters of trivalent organophosphorus acids to various functionalized acrylates and their cyclic analogues is proposed as convenient methods for the synthesis of new 2‐trimethylsiloxycarbonyl‐substituted alkylphosphonites and their derivatives under mild conditions. Also the new functionalized derivatives of these phosphonites, including amino, amido, and amino acids fragments as well as certain properties of these compounds, are presented as important precursors of new organophosphorus‐substituted derivatives of functionalized propionates and their analogues. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:418–428, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20446

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