𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of new functionalized aminomethylphosphonites and their derivatives

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
118 KB
Volume
21
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The aminomethylation of the several esters of hypophosphorous acid using chloro‐, alkoxy‐, and amino‐substituted methylamines of various structure is proposed as convenient method for the synthesis of new functionalized aminomethylphosphonites and bis(aminomethyl)phosphinates. Also O,O‐diethyl(pivaloyl)phosphonite is successfully applied in the aminomethylation as a synthetic analog of unstable diethoxyphosphine. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:361–367, 2010; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20620

📜 SIMILAR VOLUMES

Synthesis of new organophosphorus-substi
Synthesis of new organophosphorus-substituted derivatives of functionalized propionates and their analogues
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB

## Abstract Nucleophilic or radical addition of trimethylsilyl esters of trivalent organophosphorus acids to various functionalized acrylates and their cyclic analogues is proposed as convenient methods for the synthesis of new 2‐trimethylsiloxycarbonyl‐substituted alkylphosphonites and their deriv

Synthesis of new functionalized mono- an
Synthesis of new functionalized mono- and bisorganophosphorus acids and their derivatives with unsaturated and aromatic fragments
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 219 KB 👁 1 views

## Abstract Convenient procedures for the synthesis of functionalized mono‐ and bisorganophosphorus acids and their derivatives with unsaturated and aromatic fragments, starting from the available derivatives of trivalent phosphorus acids, unsaturated and aromatic aldehydes, and carboxylic acid chl

Synthesis of functionalized 1-trimethyls
Synthesis of functionalized 1-trimethylsiloxy-substituted O-trimethylsilyl alkylphosphonites and their derivatives
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 457 KB

## Abstract Nucleophilic addition of trimethylsilyl esters of tricoordinate organophosphorus acids to various functionalized aldehydes with vinyl, aryl, and heterocyclic fragments is proposed as a convenient method for the synthesis of new 1‐trimethylsiloxysubstituted alkylphosphonites and their de