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Synthesis of new organophosphorus-substituted mono- and bis(trimethylsilyl)amines with PCH2N fragments and their derivatives

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
105 KB
Volume
21
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

Convenient procedures for the synthesis of new organophosphorus‐substituted mono‐ and bis(trimethylsilyl)amines with PCH~2~N moiety are proposed, starting from trimethylsilyl esters of organophosphorus acids, as well as 1,3,5‐trialkylhexahydro‐1,3,5‐triazines and N‐alkoxymethyl bis(trimethylsilyl)amines as aminomethylating reagents. Certain properties of the resulting compounds are presented. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:71–77, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20580

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