𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of bis- and tris-organophosphorus substituted amines and amino acids with PCH2N Fragments

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
130 KB
Volume
21
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The aminomethylation of the derivatives of trivalent organophosphorus acids, containing PH and POSiMe~3~ fragments with various bis‐ and tris(alkoxymethyl)amines and bis(alkoxymethyl)amino acids, is proposed as a convenient method for the synthesis of new bis‐ and trisphosphorylated amines and amino acids as well as their derivatives with four and five coordinated phosphorus. Also the three‐components systems of phosphorous acid, paraformaldehyde, and amines are thoroughly investigated via the treatment of reaction mixtures with bis(trimethylsilyl)amine. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:430–440, 2010; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20616

📜 SIMILAR VOLUMES

Synthesis and functionalization of organ
Synthesis and functionalization of organophosphorus-substituted amines with PCH2NH fragments
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 132 KB

## Abstract The convenient procedures for the synthesis of new organophosphorus‐substituted amines with the PCH~2~NH moiety are proposed, starting from the derivatives of organophosphorus PH‐acids, as well as 1,3,5‐trisubstituted hexahydro‐1,3,5‐triazines as aminomethylating reagents. Various react

Synthesis of new organophosphorus-substi
Synthesis of new organophosphorus-substituted mono- and bis(trimethylsilyl)amines with PCH2N fragments and their derivatives
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB 👁 1 views

## Abstract Convenient procedures for the synthesis of new organophosphorus‐substituted mono‐ and bis(trimethylsilyl)amines with PCH~2~N moiety are proposed, starting from trimethylsilyl esters of organophosphorus acids, as well as 1,3,5‐trialkylhexahydro‐1,3,5‐triazines and __N__‐alkoxymethyl bis(

Synthesis of Organophosphorus-Substitute
Synthesis of Organophosphorus-Substituted Amides of Carbonic Acids with PCHNC(O) and 2,6-Di-tert-butyl-4-methylphenol Fragments
✍ Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livant 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 85 KB 👁 1 views

## Abstract Convenient procedures for the synthesis of new organophosphorus‐substituted amides of various carbonic acids with PCHNC(O) and 2,6‐di‐__tert__‐butyl‐4‐methylphenol (ionol) fragments, starting from the adducts of imines and acyl chlorides, are proposed. Some properties of the new synthes