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Synthesis and functionalization of organophosphorus-substituted amines with PCH2NH fragments

✍ Scribed by Andrey A. Prishchenko; Mikhail V. Livantsov; Olga P. Novikova; Ludmila I. Livantsova; Valery S. Petrosyan

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
132 KB
Volume
21
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The convenient procedures for the synthesis of new organophosphorus‐substituted amines with the PCH~2~NH moiety are proposed, starting from the derivatives of organophosphorus PH‐acids, as well as 1,3,5‐trisubstituted hexahydro‐1,3,5‐triazines as aminomethylating reagents. Various reactions of functionalization (such as acylation, carboxyethylation, pyridylethylation, and aminoethylation) of the obtained organophosphorus‐substituted amines are presented. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:236–241, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20602

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